The plagioclase series runs from albite, Na(AlSi3O8), to anorthite, Ca(Al2Si2O8). Sodium and silicon are exchanged for calcium and aluminium together, because swapping Na+ for Ca2+ alone would leave the structure with the wrong charge.
- precision note: Inferred from the two approved formulas, which differ by exactly this coupled exchange; the cited source gives the formulas rather than the substitution mechanism.
Evidence support: Supported by the cited evidence one source
Evidence: Commission on New Minerals, Nomenclature and Classification, International Mineralogical Association 2026 Primary authority