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LITHOEN

Manufacturing process

Precursor infiltration and pyrolysis

Also known as PIP, polymer infiltration and pyrolysis

A process in which a liquid preceramic polymer is infiltrated into a fibre preform and pyrolysed into ceramic, repeated many times because the precursor shrinks. It suits complex shapes at moderate temperature.

Classification

matrix families
CERAMIC

How this record is known

3
Settled consensus
Cited as the accepted position of the discipline.

3 of 3 claims on this page cite at least one registered source. Counts describe how each statement is known, not how likely it is to be true.

What Lithoen records

Each claim states how it is known and cites its evidence.

EstablishedModerate-temperature, deep-penetrating route suited to complex shapes.

Because pyrolysis runs at relatively low temperature, no more than about 1500 °C, precursor infiltration and pyrolysis is unlikely to damage carbon fibres, and because the liquid precursor penetrates deeply it can make complex shapes; the precursor chemistry can also be designed to tailor the fibre–matrix bond.

  • precision note: The review gives the pyrolysis temperature as no more than 1500 °C; it is an upper bound, not a process setting, and is not published as a quantity.

Evidence support: Supported by the cited evidence one source

Evidence: Ruize 2025 Peer-reviewed

EstablishedPorosity and cracking from shrinkage, many slow cycles, possible fibre degradation.

Precursor infiltration and pyrolysis leaves open porosity, pores and micro-cracks from gas evolution and the shrinkage of precursor to ceramic, which can later admit oxygen; the many cycles make it slow and costly; and carbon fibres can be degraded by reaction with the precursors, which interphase coatings protect against at the cost of reducing infiltration into the fibre tows.

Evidence support: Supported by the cited evidence 2 sources, multiple sources, independence unknown

Evidence: Jon 2020 Peer-reviewed; Ruize 2025 Peer-reviewed

EstablishedLiquid preceramic polymer infiltrated, cross-linked and pyrolysed, repeated many times.

In precursor infiltration and pyrolysis a liquid preceramic polymer is infiltrated into a fibre preform, cross-linked and pyrolysed at elevated temperature so that it converts to ceramic inside the preform; because conversion is incomplete, gas is evolved and the precursor shrinks, the cycle is repeated many times — often a dozen or more — until the matrix is dense enough.

Evidence support: Supported by the cited evidence 2 sources, multiple sources, independence unknown

Evidence: Jon 2020 Peer-reviewed; Ruize 2025 Peer-reviewed

In the knowledge graph

Record last updated 2026-10-30. Corrections follow the published corrections policy; superseded claims are retained, never silently edited.